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Strain
Si- eSiC
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Silicon-carbon (Si:C) is one materials choice for creating a uniaxial tensile
stressor via epitaxy in the source/drain region of NMOS transistors. The concept of
using Si:C is to epitaxially deposit a material with a smaller lattice constant
than Si within the recessed source/drain regions of the transistor to induce
tensile strain in the adjacent channel region. However, epitaxy of Si:C is much
more challenging than SiGe on the process
conditions.
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First, due to the low solubility of carbon in silicon, it is
necessary to grow the epitaxial layers at low temperatures (<600°C) to ensure
that the carbon atoms occupy substitutional sites. The impact of this low
temperature requirement is that the growth rate using traditional silicon
precursors (silane, disilane, dichlorosilane) is reduced, requiring longer
processing times per wafer. The low temp high Gr precursors to be discussed are Silcore (trisilane), dichlorodisilane, and
digermylmethane.
For low temperature deposition silicon precursor it
maybe forms a reactive intermediate that has a high sticking
coefficient and is not limited by the rate of hydrogen desorption
from silicon.
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Another impact of the low temperature requirement is
the ability to create a selective process since the etch rate of silicon using
HCl also decreases with decreasing temperature.
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